The simplest way I can think of (unless you care if Tim is told before or after Christie):
SELECT OrderID, Employee = Manager FROM dbo.table
UNION ALL
SELECT OrderID, Employee = Worker FROM dbo.table
ORDER BY OrderID;
If order matters, and you want the manager to always always, then:
SELECT OrderID, Employee FROM
(
SELECT r = 1, OrderID, Employee = Manager
FROM dbo.Table
UNION ALL
SELECT r = 2, OrderID, Employee = Worker
FROM dbo.table
) AS x
ORDER BY OrderID, r;
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