From the documentation , it looks like you can do it like this:
<?xml version="1.0"?>
<configuration>
<configSections>
<sectionGroup name="couchbase">
<section name="bucket-a" type="Couchbase.Configuration.CouchbaseClientSection, Couchbase"/>
<section name="bucket-b" type="Couchbase.Configuration.CouchbaseClientSection, Couchbase"/>
</sectionGroup>
</configSections>
<couchbase>
<bucket-a>
<servers bucket="default">
<add uri="http://127.0.0.1:8091/pools" />
</servers>
</bucket-a>
<bucket-b>
<servers bucket="beernique" bucketPassword="b33rs">
<add uri="http://127.0.0.1:8091/pools" />
</servers>
</bucket-b>
</couchbase>
<startup>
<supportedRuntime version="v4.0" sku=".NETFramework,Version=v4.0"/>
</startup>
</configuration>
Neild source
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