Z3 does not have APIs or tactics for converting formulas to DNF. However, he maintains the goal break in many sub-goals using tactics split-clause. Given the input formula in CNF, if we apply this tactic exhaustively, each output sub-goal can be seen as a big conjunction. Here is an example of how to do this.
http://rise4fun.com/Z3/zMjO
Here is the command:
(apply (then simplify (repeat (or-else split-clause skip))))
repeat , .
split-clause , . or-else skip ( ). , , (, simplify, solve-eqs) .
, script , CNF.