AFAIK: no. XML documents can suffer from name conflicts, so namespaces are used. You cannot use XPath on XML documents without registering one or more namespaces or setting prefixes for them.
XML (xmlns="<namespace identifier>"), . , , , , , - : :
$defaultNamespace = $c->lookupNamespaceURI($c->namespaceURI);
$x->registerNamespace('epub', $defaultNamespace);
$root = $x->query('/epub:container/epub:rootfiles/epub:rootfile');