You can get rid of this gap by setting pieSliceBorderColorto "transparent". Try the following on the Google Code Playground :
function drawVisualization() {
var data = google.visualization.arrayToDataTable([
['Task', 'Hours per Day'],
['Work', 11],
['Eat', 2],
['Commute', 2],
['Watch TV', 2],
['Sleep', 7]
]);
new google.visualization.PieChart(document.getElementById('visualization')).
draw(data, {title:"So, how was your day?", pieSliceBorderColor:"transparent"});
}
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