If a site is selected in your domain, you can parse the next file using JavaScript and request assets.
If not, you cannot determine its assets (not through XHR anyway, most of the time), so you cannot preload them. You can hack it by placing the site in hidden iframe. You can also use your server as a proxy to get a list of assets and transfer it to your HTML to start preloading.
You can also try using this tag meta...
<link rel="prefetch" href="/images/big.jpeg">
Source .
This is a lot of effort, maybe not so much though.
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