The first two arguments addstrmust be string, col integers, but your list:
To make a square like this:
for x in range(23,42):
for y in range(5,24):
stdscr.addstr(y, x, '#')
To fill colors, blink, bold, etc., you can use the attribute registered in the function:
from curses import *
def main(stdscr):
start_color()
stdscr.clear()
stdscr.addstr(0, 0, "Fig: SQUARE", A_UNDERLINE|A_BOLD)
init_pair(1, COLOR_RED, COLOR_WHITE)
init_pair(2, COLOR_BLUE, COLOR_WHITE)
pair = 1
for x in range(3, 3 + 5):
for y in range(4, 4 + 5):
pair = 1 if pair == 2 else 2
stdscr.addstr(y, x, '#', color_pair(pair))
stdscr.addstr(11, 0, 'Press Key to exit: ')
stdscr.refresh()
stdscr.getkey()
wrapper(main)
Output:

Old answer:
Do it diagonally:
for c, r in zip(range(23,42), range(5,24)) :
stdscr.addstr(c, r, '#')
Example code for filling the diagonal:
code x.py
from curses import wrapper
def main(stdscr):
stdscr.clear()
for r, c in zip(range(5,10),range(10, 20)) :
stdscr.addstr(r, c, '#')
stdscr.addstr(11, 0, 'Press Key to exit: ')
stdscr.refresh()
stdscr.getkey()
wrapper(main)
run: python x.py, :

, :
from curses import wrapper
def main(stdscr):
stdscr.clear()
for r in range(5,10):
for c in range(10, 20):
stdscr.addstr(r, c, '#')
stdscr.addstr(11, 0, 'Press Key to exit: ')
stdscr.refresh()
stdscr.getkey()
wrapper(main)
:

PS: , , .